Mots-clés
Équipe
CEMEF
Biographie
Nathanael Guigo est un chercheur spécialisé dans le domaine des polymères biosourcés et des matériaux durables. Ses travaux se concentrent sur l’étude des mécanismes de réticulation, de recyclage et de fonctionnalisation de polymères et composites, ainsi que sur le développement de résines thermoplastiques et thermodurcissables issus de ressources renouvelables. Ses recherches abordent notamment l’optimisation des propriétés thermiques, mécaniques et structurales de polymères comme le poly(butylène furanoate) (PBF), le poly(éthylène 2,5-furandicarboxylate) (PEF) ou encore les résines furaniques à base d’alcool furfurylique, des humines industrielles ou des lignines issues de procédés de bioraffinerie. Il intègre dans ses recherches des approches d’analyses thermiques et spectroscopiques avancées. Il explore également des procédés innovants pour le recyclage physique des plastiques difficiles à recycler (ex. ABS, composites bois polymère), tels que la dissolution/précipitation ou la solvolyse, et contribue à l’élaboration de matériaux biocompatibles pour des applications en médecine régénérative.
Publication(s)
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2026
Dissolution kinetics of poly(styrene-co-acrylonitrile) below and above its glass transition temperature DOI : 10.1016/j.mtcomm.2025.114556
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2025
Polyurethane free biobased epoxy binder for cork agglomeration DOI : 10.1016/j.indcrop.2025.120972
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2025
Unveiling the uncommon crystallization features of 3,4-PEF, a thermal and DFT study DOI : 10.1016/j.polymer.2025.128065
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2025
Shedding light on the impact of a dissolution-precipitation recycling process on crystallization and thermal stability of PBS DOI : 10.1016/j.polymertesting.2025.108924
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2025
Exploiting epoxy-based monomers from biobased ferulic acid and furfuryl amine for a new set of bio-derived materials DOI : 10.1016/j.reactfunctpolym.2025.106443
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2025
Catalytic Effect of Eutectic Hardeners to Polymerize Epoxidized Vegetable Oil for the Synthesis of Fully Biobased Thermosets at Low Temperatures DOI : 10.1021/acs.macromol.4c02107
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2025
Etherification of Bio-Based Furanic Compounds via Continuous Flow DOI : 10.1002/adsu.202500526
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2025
Effect of Carbon-Based Nanofillers with Different Geometries on the Crystallization Behavior and Molecular Dynamics of Poly(Butylene Furanoate) (PBF) DOI : 10.1002/macp.202500215
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2025
Effect of mechanical recycling and virgin PBR addition on the properties of ABS recovered from WEEE: A multi-technique characterization DOI : 10.1016/j.wmb.2025.100238
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2025
Bioderived Green Algae Metabolite as a Latent Cross-Linking Agent for Protein-Based Hydrogels with High Potential for Skin Repair Applications DOI : 10.1021/acsabm.5c00010
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2025
Synthesis of semi-rigid-biobased polyesters from renewable furanic cyclobutane diacid DOI : 10.1039/d5py00485c
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2024
Tuning conditions for the amine-functionalization of carbonyls formed in biobased polyfurfuryl alcohol DOI : 10.1016/j.giant.2024.100283
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2024
Beyond 2,5-furandicarboxylic acid: status quo, environmental assessment, and blind spots of furanic monomers for bio-based polymers DOI : 10.1039/d4gc00784k
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2024
Poly(ethylene 2,5-furandicarboxylate) pole figures to determine the microstructural scheme upon uniaxial stretching: Link between orientation and crystallisation DOI : 10.1016/j.polymer.2024.127613
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2024
Editorial DOI : 10.1680/jgrma.2024.12.4.223
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2024
Sustainable alliance between nanocellulose and biobased polyfurfuryl alcohol DOI : 10.1016/j.indcrop.2024.118346
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2024
Low-Viscosity Eutectic Hardeners for More Sustainable Cross-Linking Conditions DOI : 10.1021/acsapm.4c00510
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2024
Monitoring in-situ dissolution of polystyrene-acrylonitrile (SAN) via calorimetry and spectroscopy DOI : 10.1016/j.molliq.2024.126336
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2024
Novel Biobased Copolymers Based on Poly(butylene succinate) and Cutin: In Situ Synthesis and Structure Properties Investigations DOI : 10.3390/polym16162270
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2024
Quantifying the Crystalline Polymorphism in PVDF: Comparative Criteria Using DSC, WAXS, FT-IR, and Raman Spectroscopy DOI : 10.1021/acsapm.4c01157
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2024
Exploring and Understanding the Recycling of a Bio-Based Epoxy Thermoset via Saponification DOI : 10.1021/acssusresmgt.4c00207
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2024
Oxygen-induced surface hardening and aromatization of thermoset furanic biobased resin: Origin and consequences DOI : 10.1016/j.polymdegradstab.2024.111020
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2023
Cross-Linking Mechanisms of a Rigid Plant Oil-Based Thermoset from Furfural-Derived Cyclobutane DOI : 10.1021/acs.macromol.2c02219
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2023
Mechanical Behaviour and Induced Microstructural Development upon Simultaneous and Balanced Biaxial Stretching of Poly(ethylene furandicarboxylate), PEF DOI : 10.3390/polym15030661
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2023
Impact of amine functionalization on poly(furfuryl alcohol) properties DOI : 10.1016/j.polymertesting.2023.108248
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2023
Poly(hexylene vanillate): Synthetic Pathway and Remarkable Properties of a Novel Alipharomatic Lignin-Based Polyester DOI : 10.1021/acssuschemeng.2c06507
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2023
Kinetics and mechanism of nonisothermal crystallization of biobased poly(hexamethylene 2,5-furan dicarboxylate) DOI : 10.1016/j.polymer.2023.126366
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2023
Structural Variations in Biobased Polyfurfuryl Alcohol Induced by Polymerization in Water DOI : 10.3390/polym15071745
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2023
Revealed pathways of furan ring opening and surface crosslinking in biobased polyfurfuryl alcohol DOI : 10.1016/j.eurpolymj.2023.111869
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2023
Photopolymerization of furan-based monomers: Exploiting UV-light for a new age of green polymers DOI : 10.1016/j.reactfunctpolym.2023.105540
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2023
Cross-Linking of Biobased Monofunctional Furan Epoxy Monomer by Two Steps Process, UV Irradiation and Thermal Treatment DOI : 10.1002/macp.202200012
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2023
Sustainable approach for coating production: Room temperature curing of diglycidyl furfuryl amine and itaconic acid with UV-induced thiol-ene surface post-functionalization DOI : 10.1016/j.reactfunctpolym.2022.105486
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2022
Furanic Humins from Biorefinery as Biobased Binder for Bitumen DOI : 10.3390/polym14051019
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2022
Thiol-ene biobased networks: Furan allyl derivatives for green coating applications DOI : 10.1016/j.porgcoat.2022.107203
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2022
Developing future visions for bio-plastics substituting PET – A backcasting approach DOI : 10.1016/j.spc.2022.02.019
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2022
Monitoring the Degree of Carbonyl-Based Open Structure in a Furanic Macromolecular System DOI : 10.1021/acs.macromol.1c02098
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2022
Review of Wood Modification and Wood Functionalization Technologies DOI : 10.3390/f13071004
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2022
Conditions to Control Furan Ring Opening during Furfuryl Alcohol Polymerization DOI : 10.3390/molecules27103212
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2022
Exploring New Horizons for Bio-Based Poly(furfuryl alcohol) by Exploiting Functionalities Offered by Side Reactions DOI : 10.1021/acsmacrolett.2c00427
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2022
A proposal for enhanced microstructural development of Poly(ethylene 2,5-furandicarboxylate), PEF, upon stretching: On strain-induced crystallization and amorphous phase stability improvement DOI : 10.1016/j.polymer.2022.124775
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2022
Hot-lithography 3D printing of biobased epoxy resins DOI : 10.1016/j.polymer.2022.125097
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2022
Radical Oxidation of Itaconic Acid-Derived Unsaturated Polyesters under Thermal Curing Conditions DOI : 10.1021/acs.macromol.2c01682
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2021
Cross-linking behavior of eutectic hardeners from natural acid mixtures DOI : 10.1039/d0gc03172k
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2021
Spent Coffee Grounds as Property Enhancing Filler in a Wholly Bio-Based Epoxy Resin DOI : 10.1002/mame.202100323
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2021
Natural fibre composites with furanic thermoset resins. Comparison between polyfurfuryl alcohol and humins from sugar conversion DOI : 10.1016/j.jcomc.2021.100109
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2021
Cationic UV Curing of Bioderived Epoxy Furan-Based Coatings: Tailoring the Final Properties by in Situ Formation of Hybrid Network and Addition of Monofunctional Monomer DOI : 10.1021/acssuschemeng.1c06939
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2021
Biobased furanic derivatives for sustainable development DOI : 10.1039/d1gc90124a
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2021
Unravelling the para- and ortho-benzene substituent effect on the glass transition of renewable wholly (hetero-)aromatic polyesters bearing 2,5-furandicarboxylic moieties DOI : 10.1016/j.eurpolymj.2021.110413
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2021
Towards increased sustainability for aromatic polyesters: Poly(butylene 2,5-furandicarboxylate) and its blends with poly(butylene terephthalate) DOI : 10.1016/j.polymer.2020.123157
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2021
A rigid plant oil-based thermoset with a furfural-derived cyclobutane cross-linker DOI : 10.1039/d0gc04323k
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2021
Recommendations for replacing PET on packaging, fiber, and film materials with biobased counterparts DOI : 10.1039/d1gc02082j
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2021
Comparative analysis of the mechanical behaviour of pef and pet uniaxial stretching based on the time/temperature superposition principle DOI : 10.3390/polym13193295
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2021
Suberin from Cork as a Tough Cross-Linker in Bioepoxy Resins DOI : 10.1021/acsapm.1c00927
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2021
Non-furanic humins-based non-isocyanate polyurethane (NIPU) thermoset wood adhesives DOI : 10.3390/polym13030372
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2020
Eutectic hardener from food-based chemicals to obtain fully bio-based and durable thermosets DOI : 10.1039/d0gc00311e
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2020
Understanding of strain-induced crystallization developments scenarios for polyesters: Comparison of poly(ethylene furanoate), PEF, and poly(ethylene terephthalate), PET DOI : 10.1016/j.polymer.2020.122755
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2020
Ambient temperature self‐blowing tannin–humins biofoams DOI : 10.3390/polym12112732
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2020
Conformational Change Analysis of Poly(ethylene 2,5-furandicarboxylate) and Poly(ethylene terephthalate) under Uniaxial Stretching DOI : 10.1021/acs.macromol.0c00691
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2020
Polymerization kinetic pathways of epoxidized linseed oil with aliphatic bio-based dicarboxylic acids DOI : 10.1002/pol.20200118
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2020
Humin based resin for wood modification and property improvement DOI : 10.1039/c9gc03620b
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2020
A Perspective on PEF Synthesis, Properties, and End-Life DOI : 10.3389/fchem.2020.00585
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2020
Strain-induced crystallization of poly(ethylene 2,5-furandicarboxylate). Mechanical and crystallographic analysis DOI : 10.1016/j.polymer.2019.122126
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2019
Kinetics and chemorheological analysis of cross-linking reactions in humins DOI : 10.3390/polym11111804
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2019
Investigation on the role of the alkyl side chain of cardanol on benzoxazine polymerization and polymer properties DOI : 10.1016/j.eurpolymj.2019.07.026
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2019
Suberin/ trans-Cinnamaldehyde Oil Nanoparticles with Antimicrobial Activity and Anticancer Properties When Loaded with Paclitaxel DOI : 10.1021/acsabm.9b00408
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2019
Green' composites prepared from polyfurfuryl alcohol and cork residues: Thermal and mechanical properties DOI : 10.1016/j.compositesa.2019.105473
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2019
All ‘green’ composites comprising flax fibres and humins’ resins DOI : 10.1016/j.compscitech.2018.12.008
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2019
Synthesis and characterization of two new biobased poly(pentylene 2,5-furandicarboxylate-co-caprolactone) and poly(hexamethylene 2,5-furandicarboxylate-co-caprolactone) copolyesters with enhanced enzymatic hydrolysis properties DOI : 10.1016/j.polymdegradstab.2019.01.004
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2019
Crystallization of polytetrafluoroethylene in awide range of cooling rates: Nucleation and diffiusion in the presence of nanosilica clusters DOI : 10.3390/molecules24091797
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2019
Thermal Properties of Biobased Polymers: Furandicarboxylic Acid (FDCA)-Based Polyesters DOI : 10.1007/12_2019_51
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2018
Humins from Biorefineries as Thermoreactive Macromolecular Systems DOI : 10.1002/cssc.201802066
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2018
Chain Structure and Molecular Weight Dependent Mechanics of Poly(ethylene 2,5-furandicarboxylate) Compared to Poly(ethylene terephthalate) DOI : 10.1021/acs.macromol.8b01831
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2018
Strain induced crystallization in biobased Poly(ethylene 2,5-furandicarboxylate) (PEF); conditions for appearance and microstructure analysis DOI : 10.1016/j.polymer.2018.10.054
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2018
Biaxial Orientation of Poly(ethylene 2,5-furandicarboxylate): An Explorative Study DOI : 10.1002/mame.201700507
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2018
FA polymerization disruption by protic polar solvents DOI : 10.3390/polym10050529
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2018
Opening Furan for Tailoring Properties of Bio-based Poly(Furfuryl Alcohol) Thermoset DOI : 10.1002/cssc.201800620
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2018
Thermal Analysis of Biobased Polymers and Composites DOI : 10.1016/B978-0-444-64062-8.00002-4
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2018
Tailored design of renewable copolymers based on poly(1,4-butylene 2,5-furandicarboxylate) and poly(ethylene glycol) with refined thermal properties DOI : 10.1039/c7py01627a
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2018
Humins valorization: From well-defined properties to potential applications DOI : 10.1063/1.5045888
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2017
Preparation and characterization of poly(ethylene 2,5-furandicarboxylate/nanocrystalline cellulose composites via solvent casting DOI : 10.1515/polyeng-2017-0042
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2017
Preparation and crystallization behavior of poly(ethylene 2,5-furandicarboxylate)/cellulose composites by twin screw extrusion DOI : 10.1016/j.carbpol.2017.07.006
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2017
Kinetics of doublet formation in bicomponent magnetic suspensions: The role of the magnetic permeability anisotropy DOI : 10.1103/PhysRevE.96.062604
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2017
Influence of organically modified montmorillonite and sepiolite clays on the physical properties of bio-based poly(ethylene 2,5-furandicarboxylate) DOI : 10.1016/j.compositesb.2016.11.008
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2017
Further insights into the kinetics of thermal decomposition during continuous cooling DOI : 10.1039/c7cp00573c
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2017
Modelling the non-isothermal crystallization of polymers: Application to poly(ethylene 2,5-furandicarboxylate) DOI : 10.1016/j.tca.2017.02.008
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2017
Impact of Silica Nanoclusters on Furfuryl Alcohol Polymerization and Molecular Mobility DOI : 10.1021/acs.jpcc.6b12882
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2017
Crystallization of Poly(butylene succinate) on Rapid Cooling and Heating: Toward Enhanced Nucleation by Graphene Nanosheets DOI : 10.1021/acs.jpcc.7b02887
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2017
Humins as promising material for producing sustainable carbohydrate-derived building materials DOI : 10.1016/j.conbuildmat.2016.11.019
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2016
Glass transition dynamics and cooperativity length of poly(ethylene 2,5-furandicarboxylate) compared to poly(ethylene terephthalate) DOI : 10.1039/c6cp01227b
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2016
Morphology and thermal properties of novel clay-based poly(ethylene 2,5-furandicarboxylate) (PEF) nanocomposites DOI : 10.1039/c6ra09114h
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2016
Fast Crystallization and Melting Behavior of a Long-Spaced Aliphatic Furandicarboxylate Biobased Polyester, Poly(dodecylene 2,5-furanoate) DOI : 10.1021/acs.iecr.6b00811
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2016
Isoconversional kinetics by fast scanning calorimetry DOI : 10.1007/978-3-319-31329-0_7
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2016
Nucleation and Self-Nucleation of Bio-Based Poly(ethylene 2,5-furandicarboxylate) Probed by Fast Scanning Calorimetry DOI : 10.1002/mame.201500418
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2015
Thermomechanical behavior of a novel biobased poly(furfurylalcohol)/silica nanocomposite elaborated by smart functionalization of silica nanoparticles DOI : 10.1016/j.polymdegradstab.2015.04.018
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2015
Synthesis, properties and thermal behavior of poly(decylene-2,5-furanoate): A biobased polyester from 2,5-furan dicarboxylic acid DOI : 10.1039/c5ra13324f
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2015
On the bio-based furanic polyesters: Synthesis and thermal behavior study of poly(octylene furanoate) using fast and temperature modulated scanning calorimetry DOI : 10.1016/j.eurpolymj.2015.04.011
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2015
Partial periodate oxidation and thermal cross-linking for the processing ofthermosetall-cellulose composites DOI : 10.1016/j.compscitech.2015.05.022
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2015
Isothermal crystallization kinetics of poly (ethylene 2,5-furandicarboxylate) DOI : 10.1002/mame.201400376
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2015
Copolymerization as a Strategy to Combine Epoxidized Linseed Oil and Furfuryl Alcohol: The Design of a Fully Bio-Based Thermoset DOI : 10.1002/cssc.201501259
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2014
Surface modification of cellulose microfibrils by periodate oxidation and subsequent reductive amination with benzylamine: a topochemical study DOI : 10.1007/s10570-014-0459-0
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2014
Non-isothermal Crystallization Kinetics of Biobased Poly(ethylene 2,5-furandicarboxylate) Synthesized via the Direct Esterification Process DOI : 10.1002/macp.201400316
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2014
Melt and glass crystallization of PDMS and PDMS silica nanocomposites DOI : 10.1039/c4cp00164h
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2014
Valorization of biorefinery side-stream products: Combination of humins with polyfurfuryl alcohol for composite elaboration DOI : 10.1021/sc5003769
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2013
Crystallization behaviour of polytetrafluoroethylene over very large cooling rate domains DOI : 10.4028/www.scientific.net/AMR.747.201
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2013
Elaboration and characterization of a novel biobased poly(furfurylalcohol)/silica nanocomposite DOI : 10.4028/www.scientific.net/AMR.747.657
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2013
Nonisothermal crystallization of polytetrafluoroethylene in a wide range of cooling rates DOI : 10.1021/jp311196g
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2012
Atypical gelation in gelatin solutions probed by ultra-fast calorimetry DOI : 10.1039/c2sm25737h
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2012
Gelation on heating of supercooled gelatin solutions DOI : 10.1002/marc.201100748
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2012
Complex kinetic pathway of furfuryl alcohol polymerization catalyzed by green montmorillonite clays DOI : 10.1021/jp301439q
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2010
Shear induced structuration of liquid crystalline epoxy thermosets DOI : 10.1016/j.eurpolymj.2010.04.001
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2010
Eco-friendly composite resins based on renewable biomass resources: Polyfurfuryl alcohol/lignin thermosets DOI : 10.1016/j.eurpolymj.2010.02.010
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2009
New insights on the thermal degradation pathways of neat poly(furfuryl alcohol) and poly(furfuryl alcohol)/SiO2 hybrid materials DOI : 10.1016/j.polymdegradstab.2009.03.008
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2009
Innovative green nanocomposites based on silicate clays/lignin/natural fibres DOI : 10.1016/j.compscitech.2009.05.001
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2009
Integral, differential and advanced isoconversional methods. Complex mechanisms and isothermal predicted conversion-time curves DOI : 10.1016/j.chemolab.2009.02.002
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2009
Molecular mobility and relaxation process of isolated lignin studied by multifrequency calorimetric experiments DOI : 10.1039/b812512k
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2007
Chemorheological analysis and model-free kinetics of acid catalysed furfuryl alcohol polymerization DOI : 10.1039/b707950h
Projets
- 2025-2029 SUSPENSE Responsable scientifique The SUSPENSE project (HORIZON-JU-CBE-2024-IA-06) aims to develop and demonstrate innovative safe and sustainable bio-based adhesives for wood board and wood panels to replace conventional fossil-based adhesives, which are harmful to the environment and human health. The project focuses on creating adhesives from renewable feedstocks such as bio-acids, polyphenolics, proteins and other bio-derived materials. Scientific leader of WP3 on recycling strategies of wood-based adhesives and panels.
Enseignements
Matériaux pour l'ingénieur
L'activité en présentiel (27 heures) est structurée en séances plénières en amphi (12 heures), en séances en petites classes (PC) (12 heures) à effectif plus réduit, en restitution des TP devant un jury (30 minutes). Elle inclut également l'examen écrit (2h30). Le travail personnel des élèves (18heures) comprend (en plus de l'activité démontage/remontage de moteur mentionnée plus haut) : Un QCM d’auto-évaluation (30 min) sur les pré-requis. Cette auto-évaluation est réalisée en amont du premier cours pour cerner les points forts et faibles des élèves et mettre ensuite l’accent sur certains aspects pendant les enseignements en face-à-face pédagogique. Un devoir sur les diagrammes de phases (2 heures) Un devoir sur le vieillissement des matériaux (2 heures) Des travaux pratiques au CMAT (6 heures) : 13 TP sont réalisés par groupes de 4 à 5 élèves, avec encadrement d'ingénieurs et techniciens du Centre, mais aussi de doctorants, les sujets de TP étant pour la plupart connexes aux sujets de thèse en cours. Restitution orale de 20 min par TP en fin de journée dans deux sessions en parallèle. Les élèves réalisent donc un des TP et participent/assistent à la moitié des restitutions en fin de journée. Deux journées similaires sont organisées, de façon à accueillir l'ensemble de la promotion. Révision de l’examen final (5 heures)
Direction(s) de thèse(s)
- 2025 Effet des relations structure-propriété lors de procédés de polymérisation d'un préimprégné à matrice poly(alcool furfurylique). BEN AYED Hiba
- 2017 Etude de la microstructure induite du PEF, un polymère biosourcé, lors d’étirages uniaxiaux et biaxiaux au-dessus de la transition alpha FORESTIER Emilie
